| 1 | Mercy Catholic CollegeChatswood | Chatswood | 1134 | 728 | 12.9 |
| 2 | Marist College EastwoodEastwood | Eastwood | 1119 | 976 | 13.9 |
| 3 | St Clare's CollegeWaverley | Waverley | 1118 | 773 | 13.9 |
| 4 | Brigidine College RandwickRandwick | Randwick | 1114 | 851 | 13.6 |
| 5 | St Leo's Catholic CollegeWahroonga | Wahroonga | 1113 | 1,055 | 13.5 |
| 6 | Marist Sisters' College WoolwichWoolwich | Woolwich | 1101 | 937 | 13.4 |
| 7 | Marcellin CollegeRandwick | Randwick | 1100 | 964 | 13.5 |
| 8 | St John XXIII Catholic College (Secondary)Stanhope Gardens | Stanhope Gardens | 1097 | 1,166 | 14.0 |
| 9 | Gilroy Catholic CollegeCastle Hill | Castle Hill | 1096 | 1,307 | 14.2 |
| 9 | St Francis Xavier's CollegeHamilton | Hamilton | 1096 | 959 | 10.5 |
| 11 | St Ursula's CollegeKingsgrove | Kingsgrove | 1095 | 1,110 | 13.5 |
| 12 | St Patrick's College SutherlandSutherland | Sutherland | 1093 | 1,227 | 13.7 |
| 13 | Domremy Catholic CollegeFive Dock | Five Dock | 1091 | 858 | 14.1 |
| 13 | St Paul's Catholic CollegeManly | Manly | 1091 | 468 | 11.1 |
| 15 | Marist Catholic College PenshurstMortdale | Mortdale | 1090 | 1,343 | 13.9 |
| 15 | Trinity Catholic CollegeAdamstown | Adamstown | 1090 | 849 | 11.6 |
| 17 | St Aloysius College CronullaCronulla | Cronulla | 1089 | 482 | 11.8 |
| 17 | St Patrick's Marist CollegeDundas | Dundas | 1089 | 1,070 | 14.6 |
| 19 | St Columba's Catholic CollegeSpringwood | Springwood | 1088 | 1,112 | 13.0 |
| 19 | St Luke's Catholic College (Secondary)Marsden Park | Marsden Park | 1088 | 940 | 15.6 |
| 21 | Catherine McAuley WestmeadWestmead | Westmead | 1087 | 1,210 | 14.5 |
| 22 | Our Lady of Mercy Catholic College BurraneerCronulla | Cronulla | 1086 | 421 | 11.7 |
| 22 | Parramatta Marist High SchoolWestmead | Westmead | 1086 | 1,043 | 13.7 |
| 24 | Mater Maria Catholic CollegeWarriewood | Warriewood | 1085 | 1,098 | 13.0 |
| 25 | Bethany CollegeHurstville | Hurstville | 1083 | 1,091 | 14.4 |
| 25 | Our Lady of the Sacred Heart CollegeKensington | Kensington | 1083 | 702 | 12.9 |
| 27 | Aquinas Catholic CollegeMenai | Menai | 1082 | 1,140 | 13.8 |
| 28 | St John Bosco CollegeEngadine | Engadine | 1081 | 986 | 13.9 |
| 28 | Xavier Catholic College BallinaSkennars Head | Skennars Head | 1081 | 884 | 11.5 |
| 30 | De La Salle Catholic College, CaringbahCaringbah | Caringbah | 1078 | 536 | 11.5 |
| 30 | Santa Sophia Catholic College (Secondary)Gables | Gables | 1078 | 999 | 11.6 |
| 32 | Marist College KogarahBexley | Bexley | 1076 | 1,045 | 13.3 |
| 33 | St Joseph's Catholic CollegeEast Gosford | East Gosford | 1075 | 802 | 11.7 |
| 34 | St John Paul II Catholic College (Schofields)Schofields | Schofields | 1074 | 1,159 | 13.6 |
| 35 | Marian Catholic CollegeKenthurst | Kenthurst | 1073 | 1,035 | 13.9 |
| 36 | Mount St Patrick CollegeMurwillumbah | Murwillumbah | 1071 | 823 | 11.5 |
| 37 | Holy Spirit CollegeBellambi | Bellambi | 1069 | 1,249 | 13.0 |
| 38 | MacKillop College Port MacquariePort Macquarie | Port Macquarie | 1068 | 1,107 | 11.5 |
| 39 | De La Salle College, Revesby HeightsRevesby Heights | Revesby Heights | 1065 | 650 | 12.5 |
| 39 | Holy Cross CollegeRyde | Ryde | 1065 | 786 | 12.9 |
| 41 | St Mary's Catholic CollegeGateshead | Gateshead | 1062 | 989 | 12.0 |
| 42 | Mount St Joseph MilperraMilperra | Milperra | 1060 | 891 | 13.0 |
| 43 | St Andrews CollegeMarayong | Marayong | 1059 | 1,327 | 12.1 |
| 43 | St John's CollegeLismore | Lismore | 1059 | 774 | 11.9 |
| 45 | St Paul's Catholic CollegeGreystanes | Greystanes | 1055 | 800 | 11.3 |
| 46 | Caroline Chisholm CollegeGlenmore Park | Glenmore Park | 1054 | 1,011 | 14.0 |
| 46 | Clancy Catholic CollegeWest Hoxton | West Hoxton | 1054 | 1,211 | 13.5 |
| 48 | Casimir Catholic CollegeMarrickville | Marrickville | 1052 | 827 | 12.7 |
| 49 | Mater Dei Catholic CollegeLake Albert | Lake Albert | 1050 | 749 | 13.4 |
| 49 | St Joseph's CollegeBanora Point | Banora Point | 1050 | 838 | 10.2 |
| 51 | Nagle CollegeBlacktown | Blacktown | 1048 | 532 | 11.6 |
| 52 | Corpus Christi Catholic High SchoolOak Flats | Oak Flats | 1045 | 1,126 | 13.0 |
| 52 | St Peter's Catholic CollegeTuggerah | Tuggerah | 1045 | 1,078 | 12.8 |
| 54 | St John Paul CollegeCoffs Harbour | Coffs Harbour | 1044 | 1,062 | 12.3 |
| 55 | Corpus Christi College MaroubraMaroubra | Maroubra | 1043 | 755 | 13.2 |
| 56 | Southern Cross Catholic CollegeBurwood | Burwood | 1042 | 139 | 6.6 |
| 57 | Cerdon CollegeMerrylands | Merrylands | 1041 | 1,001 | 13.8 |
| 57 | Mount Carmel Catholic CollegeVarroville | Varroville | 1041 | 1,142 | 13.7 |
| 59 | St Benedict's Catholic CollegeOran Park | Oran Park | 1040 | 1,074 | 14.2 |
| 60 | Magdalene Catholic CollegeSmeaton Grange | Smeaton Grange | 1039 | 1,137 | 14.2 |
| 61 | Freeman Catholic CollegeBonnyrigg Heights | Bonnyrigg Heights | 1038 | 1,411 | 14.2 |
| 61 | San Clemente Catholic CollegeMayfield | Mayfield | 1038 | 605 | 11.3 |
| 63 | Xavier Catholic CollegeNorth Albury | North Albury | 1034 | 932 | 12.2 |
| 64 | McAuley Catholic CollegeClarenza | Clarenza | 1031 | 602 | 10.5 |
| 65 | St Bede's Catholic CollegeChisholm | Chisholm | 1030 | 910 | 11.4 |
| 66 | St Joseph's Catholic High SchoolAlbion Park | Albion Park | 1029 | 736 | 11.9 |
| 67 | Kildare Catholic CollegeWagga Wagga | Wagga Wagga | 1028 | 972 | 13.5 |
| 67 | St John the Evangelist Catholic High SchoolNowra | Nowra | 1028 | 935 | 12.1 |
| 69 | MacKillop College BathurstBathurst | Bathurst | 1027 | 691 | 11.7 |
| 70 | St Paul's Catholic CollegeBooragul | Booragul | 1026 | 636 | 9.9 |
| 71 | Trinity Catholic College GoulburnGoulburn | Goulburn | 1025 | 714 | 11.8 |
| 71 | Xavier CollegeLlandilo | Llandilo | 1025 | 1,185 | 13.3 |
| 73 | Penola Catholic College Emu PlainsEmu Plains | Emu Plains | 1024 | 709 | 11.6 |
| 74 | All Saints CollegeMaitland | Maitland | 1023 | 1,191 | 10.9 |
| 75 | O'Connor Catholic CollegeArmidale | Armidale | 1020 | 511 | 10.9 |
| 76 | Catherine McAuley Catholic CollegeMedowie | Medowie | 1019 | 884 | 11.5 |
| 77 | St Francis De Sales Regional CollegeLeeton | Leeton | 1018 | 666 | 12.6 |
| 78 | St Joseph's Regional CollegePort Macquarie | Port Macquarie | 1017 | 1,026 | 11.8 |
| 79 | Patrician Brothers' College BlacktownBlacktown | Blacktown | 1016 | 1,014 | 13.0 |
| 79 | Trinity Catholic CollegeAuburn | Auburn | 1016 | 1,313 | 12.7 |
| 81 | CathWest Innovation CollegeMount Druitt | Mount Druitt | 1013 | 385 | 11.8 |
| 82 | Hennessy Catholic CollegeYoung | Young | 1012 | 426 | 11.3 |
| 82 | Marian Catholic CollegeGriffith | Griffith | 1012 | 701 | 12.5 |
| 82 | St Clare's High SchoolTaree | Taree | 1012 | 630 | 10.6 |
| 85 | La Salle Catholic CollegeBankstown | Bankstown | 1011 | 1,057 | 11.1 |
| 86 | James Sheahan Catholic High School OrangeOrange | Orange | 1010 | 1,030 | 13.2 |
| 87 | Bede Polding CollegeSouth Windsor | South Windsor | 1007 | 1,101 | 12.5 |
| 87 | St Agnes Catholic High SchoolRooty Hill | Rooty Hill | 1007 | 926 | 12.3 |
| 89 | Good Samaritan Catholic CollegeHinchinbrook | Hinchinbrook | 1006 | 1,297 | 12.6 |
| 89 | St Brigid's Catholic CollegeLake Munmorah | Lake Munmorah | 1006 | 651 | 11.2 |
| 91 | St Johns College DubboDubbo | Dubbo | 1004 | 941 | 12.5 |
| 92 | John Therry Catholic CollegeRosemeadow | Rosemeadow | 1002 | 1,057 | 13.3 |
| 93 | Holy Spirit Catholic CollegeLakemba | Lakemba | 999 | 730 | 12.5 |
| 93 | St Paul's CollegeWest Kempsey | West Kempsey | 999 | 641 | 10.2 |
| 95 | Delany CollegeGranville | Granville | 996 | 348 | 10.4 |
| 95 | Emmaus Catholic CollegeKemps Creek | Kemps Creek | 996 | 674 | 11.0 |
| 95 | Newman Senior Technical CollegePort Macquarie | Port Macquarie | 996 | 327 | 9.4 |
| 95 | St Joseph's CollegeLochinvar | Lochinvar | 996 | 973 | 11.9 |
| 99 | McCarthy Catholic CollegeWest Tamworth | West Tamworth | 991 | 935 | 13.6 |
| 100 | Carroll CollegeBroulee | Broulee | 987 | 493 | 9.6 |